System.InvalidOperationException was unhandled
Message="XML 文档(1, 823)中有错误。"
Source="System.Xml"
 Message="“”(十六进制值 0x0E)是无效的字符。 行 1，位置 823。"
 Source="System.Xml"

using System;
using System.Xml.Serialization;
using System.IO;
using System.Text;
using System.Globalization;
namespace TextSerialize
{
[Serializable]
public class MyClass
{
public string Value { get; set; }
}
class Program
{
static void Main(string[] args)
{
string fileName = "d:\\1.txt";
MyClass c = new MyClass();
c.Value = string.Format("在神奇{0}天地裏誰叱咤風雨", Convert.ToChar(14));
SaveAsXML(c, fileName, Encoding.UTF8);
object o = ConvertFileToObject(fileName, typeof(MyClass), Encoding.UTF8);
MyClass d = o as MyClass;
if (d != null) Console.WriteLine(d.Value);
else Console.WriteLine("null");
Console.ReadLine();
}
/// <summary>
/// 序列化
/// </summary>
/// <param name="objectToConvert"></param>
/// <param name="path"></param>
/// <param name="encoding"></param>
public static void SaveAsXML(object objectToConvert, string path, Encoding encoding)
{
if (objectToConvert != null)
{
Type t = objectToConvert.GetType();
XmlSerializer ser = new XmlSerializer(t);
using (StreamWriter writer = new StreamWriter(path, false, encoding))
{
ser.Serialize(writer, objectToConvert);
writer.Close();
}
}
}
/// <summary>
/// 反序列化
/// </summary>
/// <param name="path"></param>
/// <param name="objectType"></param>
/// <param name="encoding"></param>
/// <returns></returns>
public static object ConvertFileToObject(string path, Type objectType, Encoding encoding)
{
object convertedObject = null;
if (!string.IsNullOrEmpty(path))
{
XmlSerializer ser = new XmlSerializer(objectType);
using (StreamReader reader = new StreamReader(path, encoding))
{
convertedObject = ser.Deserialize(reader);
reader.Close();
}
}
return convertedObject;
}
}
}

/// <summary>
/// 把一个字符串中的 低序位 ASCII 字符 替换成 &#x 字符
/// 转换 ASCII 0 - 8 -> � - 
/// 转换 ASCII 11 - 12 ->  - 
/// 转换 ASCII 14 - 31 ->  - 
/// </summary>
/// <param name="tmp"></param>
/// <returns></returns>
public static string ReplaceLowOrderASCIICharacters(string tmp)
{
StringBuilder info = new StringBuilder();
foreach (char cc in tmp)
{
int ss = (int)cc;
if (((ss >= 0) && (ss <= 8)) || ((ss >= 11) && (ss <= 12)) || ((ss >= 14) && (ss <= 32)))
info.AppendFormat("&#x{0:X};", ss);
else info.Append(cc);
}
return info.ToString();
}
/// <summary>
/// 把一个字符串中的下列字符替换成 低序位 ASCII 字符
/// 转换 � -  -> ASCII 0 - 8
/// 转换  -  -> ASCII 11 - 12
/// 转换  -  -> ASCII 14 - 31
/// </summary>
/// <param name="input"></param>
/// <returns></returns>
public static string GetLowOrderASCIICharacters(string input)
{
if (string.IsNullOrEmpty(input)) return string.Empty;
int pos, startIndex = 0, len = input.Length;
if (len <= 4) return input;
StringBuilder result = new StringBuilder();
while ((pos = input.IndexOf("&#x", startIndex)) >= 0)
{
bool needReplace = false;
string rOldV = string.Empty, rNewV = string.Empty;
int le = (len - pos < 6) ? len - pos : 6;
int p = input.IndexOf(";", pos, le);
if (p >= 0)
{
rOldV = input.Substring(pos, p - pos + 1);
// 计算 对应的低位字符
short ss;
if (short.TryParse(rOldV.Substring(3, p - pos - 3), NumberStyles.AllowHexSpecifier, null, out ss))
{
if (((ss >= 0) && (ss <= 8)) || ((ss >= 11) && (ss <= 12)) || ((ss >= 14) && (ss <= 32)))
{
needReplace = true;
rNewV = Convert.ToChar(ss).ToString();
}
}
pos = p + 1;
}
else pos += le;
string part = input.Substring(startIndex, pos - startIndex);
if (needReplace) result.Append(part.Replace(rOldV, rNewV));
else result.Append(part);
startIndex = pos;
}
result.Append(input.Substring(startIndex));
return result.ToString();
}

 static void Main(string[] args)
{
Console.WriteLine(GetLowOrderASCIICharacters("123456񐀀"));
Console.WriteLine(GetLowOrderASCIICharacters("123456"));
Console.WriteLine(GetLowOrderASCIICharacters(""));
Console.WriteLine(GetLowOrderASCIICharacters("0123 456789"));
Console.WriteLine(GetLowOrderASCIICharacters("\f"));
Console.WriteLine(GetLowOrderASCIICharacters(" =-1"));
Console.WriteLine(GetLowOrderASCIICharacters(" "));
Console.WriteLine(GetLowOrderASCIICharacters(" "));
string fileName = "d:\\1.txt";
MyClass c = new MyClass();
c.Value = string.Format("在神奇{0}天地裏誰叱咤風雨", Convert.ToChar(14));
c.Value = ReplaceLowOrderASCIICharacters(c.Value);
SaveAsXML(c, fileName, Encoding.UTF8);
object o = ConvertFileToObject(fileName, typeof(MyClass), Encoding.UTF8);
MyClass d = o as MyClass;
if (d != null)
{
d.Value = GetLowOrderASCIICharacters(d.Value);
Console.WriteLine(d.Value);
}
else Console.WriteLine("null");
Console.ReadLine();
}