public void beforeTextChanged(CharSequence s, int start, int count, int after);
public void onTextChanged(CharSequence s, int start, int before, int count);
public void afterTextChanged(Editable s);

private final TextWatcher mTextWatcher = new TextWatcher() {
 public void beforeTextChanged(CharSequence s, int start, int count, int after) {
 } 
 public void onTextChanged(CharSequence s, int start, int before, int count) {
 } 
 public void afterTextChanged(Editable s) {
  if (s.length() > 0) {
   int pos = s.length() - 1;
   char c = s.charAt(pos);
   if (c == '#') {
   //这里限制在字串最后追加#
    s.delete(pos,pos+1);
    Toast.makeText(MyActivity.this, "Error letter.",Toast.LENGTH_SHORT).show();
   }
  }
 }
};

EditText mEditor = (EditText)findViewById(R.id.editor_input);
mEditor.addTextChangedListener(mTextWatcher);