<?xml version="1.0" encoding="utf-8"?>
<accounts version="1.1.0">
 <default>127.0.0.1</default>
 <account name="127.0.0.1">
 <lastlogin>42847.9391816088</lastlogin>
 <manualurl version="5.0.22-community-nt"></manualurl>
 <connection>
  <database></database>
  <host>127.0.0.1</host>
  <library>
  <filename>libMySQL.dll</filename>
  <tunnel_url></tunnel_url>
  </library>
  <password encode="none">root</password>
  <port>3306</port>
  <user>root</user>
 </connection>
 <favorites />
 </account>
 <account name="daqin">
 <lastlogin>0</lastlogin>
 <manualurl version=""></manualurl>
 <connection>
  <database></database>
  <host>127.0.0.1</host>
  <library>
  <filename>libMySQL.dll</filename>
  <tunnel_url></tunnel_url>
  </library>
  <password encode="none">daqin</password>
  <port>3306</port>
  <user>daqin</user>
 </connection>
 <favorites />
 </account>
</accounts>

# -*- coding: utf-8 -*-
"""
Created on 2017-04-22 22:53:35

@author: codegay
"""
import os
from pyquery import PyQuery as pyq

xmlpath = os.environ['appdata']+r'\MySQL-Front\Accounts.xml'

root = pyq(filename=xmlpath)
for r in root('connection').items():
 print("----------------------------------------------")
 print('host:',r('host').text())
 print('username:',r('user').text())
 print('password:',r('password').text())

----------------------------------------------
host: 127.0.0.1
username: root
password: root
----------------------------------------------
host: 127.0.0.1
username: daqin
password: daqin